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Los orbitales _d_ tienen formas más complejas que los _s_ y _p_. Tienen _l = 2_. Cada nivel de energía a partir de _n = 3_ tiene cinco orbitales _d_, cada uno con una forma distinta y orientaciones diferentes en el espacio. La forma y la orientación de los orbitales _d_ son fundamentales para la formación de complejos de metales de transición. Estos orbitales permiten una variedad de interacciones y enlaces químicos, lo que da lugar a propiedades únicas de los metales de transición, como su capacidad para formar diferentes estados de oxidación y su comportamiento catalítico.
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