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Think about the way electrons fill up atomic orbitals. The Aufbau principle and Hund's rule dictate the rules, but in molecular systems, it's a bit more nuanced. The **pseudo energy order** is a consequence of the complex interplay of these factors, leading to a modified or seemingly unusual order of MO filling. For example, consider the molecular orbitals formed by the combination of atomic orbitals. Atomic orbitals like s and p orbitals from different atoms can mix, resulting in bonding and antibonding molecular orbitals. The interaction and mixing of these orbitals are a major cause of the pseudo energy order. The extent of this mixing and the resulting energy levels of the MOs depend on the relative energies of the atomic orbitals and the overlap between them. This is why the simple application of atomic orbital rules does not always apply to molecular orbitals, but it is necessary to consider the pseudo energy order.
